|
AFC
|
alkaline
fuel cell; with alkaline electrolyte, operating
temperature 60 to 90°C; fuel: pure hydrogen;
can only be operated with pure oxygen or with
air if the CO2 has been removed;
state of the art: so far used mainly in military
applications and space travel; presently developed
and manufactured by ZeTek Power for terrestrial
applications. |
|
|
all
organic substances: plants, wood chips, bales
of straw, liquid manure, organic wastes etc. |
|
biomass
converter
|
(technical)
system that converts organic feedstock (biomass)
into a technically usable energy
carrier: e.g. steam
reformer. |
|
boil-off
loss
|
amount
of gas that vaporizes in a liquid
gas storage through external heating (ambient
temperature). The gas will only be vented when
the operating pressure is exceeded. |
|
|
a
catalyst is a material that facilitates, accelerates
etc. a chemical reaction retaining its own properties
and without being consumed. |
|
catalytic
combustion
|
in
a catalytic combustion the combustion temperature
is reduced by a catalyst.
Lower temperatures result in near zero nitrous
oxide (NOx) emissions. |
|
CGH2
or CH2
|
compressed
gaseous hydrogen |
|
|
storage
device for gases (e.g. hydrogen,
natural gas, nitrogen) at room temperature under
high pressure (typically some 20 MPa). |
|
compressor
|
device
for increasing gas pressure or gas flow rate. |
|
|
special
type of graphite
storage. Carbon is able to adsorb hydrogen. Different qualities of carbon can adsorb higher
quantities of hydrogen under certain temperature
and pressure conditions than could be stored
without the carbon under the same conditions.
Temperatures are below 0°C (cryogenic)
and above boiling temperature of hydrogen (20 K).
The pressure levels are above 5 MPa. |
|
|
Greek
krýos: cold, frost. Applied to gases cryogenic
refers to low temperatures where the gases are
in their liquid phase. For natural gas the boiling
temperature (where the phase transition from
liquid to gaseous occurs) is -161.5°C (111.5 K)
and for hydrogen it
is -253°C (20 K). |
|
dissociation
of water at high temperatures
|
above
2000 K (1700°C approximately), a temperature
that can be achieved in solar furnaces without
major problems, water is split into hydrogen
and oxygen. Ceramic membranes permitting the
permeation of hydrogen but inhibiting that of
oxygen are used for the gas separation. This
process is in a very early stage of development. |
|
DMFC
|
direct
methanol fuel cell;
fuel: methanol; state of the art: basic research. |
|
electro
farming
|
concept
that comprises the conversion of energy
crops (biomass) via
steam reforming
and fuel cells into
electricity. This way, in principle, electricity
is farmed". |
|
|
In
an electrolyzer, an electric current splits
water into hydrogen
and oxygen. Reverse process of the fuel
cell. |
|
|
medium
(gaseous, e.g. natural gas, hydrogen;
liquid, e.g. petrol, biofuels; solid, e.g. wood,
coal) in which energy is stored in chemical
form; by means of energy carriers energy is
storable and transportable. Non-material energy
carriers are e.g. electricity and solar radiation.
Within certain limits and with certain losses
energy carriers can be converted into one another
(e.g. solar radiation into electricity, electricity
into hydrogen, hydrogen into electricity, electricity
into light etc.). |
|
|
plants
that are grown for the sole purpose of energy
production, not for food production (e.g. rape
used for the production of biofuels). The growing
of energy crops is not yet very wide-spread. |
|
|
A
fuel cell is an electrochemical device in which
hydrogen and oxygen combine in an controlled
manner (in contrast to combustion or explosion)
to directly produce an electric current and
heat. Reverse process of electrolyzer. |
|
full
composite storage
|
storage
tank produced entirely from composite materials.
Presently, the market introduction of full composite
compressed
gas storages takes place. |
|
GH2
|
gaseous
hydrogen. At room temperature (above -253°C or 20 K,
to be exact) hydrogen is gaseous independent
of the pressure. |
|
|
carbon
is able to adsorb hydrogen.
The amount of adsorbed hydrogen depends on temperature,
pressure and the quality/ structure of the carbon
used. Carbon structures in the nanometers range
(one nanometer corresponds to 10-9
meters), e.g. balls, tubes or fibers, seem to
be very promising. The developments are in a
very early stage. |
|
H2
|
hydrogen |
|
H2/O2
steam generator
|
device
that produces steam via the reaction of hydrogen and oxygen. The subsequent injection of water
allows a temperature control between 200 and
2000°C. H2/O2 steam generators
have been developed as a spinning reserve of
large power plants, but have not yet been applied. |
|
heating
value
|
energy
content of an energy
carrier. Upper and lower heating value are
distinguished. Upper heating value: total energy
content of the energy carrier. Lower heating
value: energy content reduced by the condensation
energy (latent heat) of the product gas (the
steam in the product gas, to be exact). |
|
|
H
is the chemical symbol for hydrogen, the lightest
element of the table of elements and the most
abundant element of the universe. In general,
hydrogen will be found in molecular form, i.e.
as a hydrogen molecule composed of two hydrogen
atoms (H2), or in other compounds
(e.g. in water H2O, organic
substances). Hydrogen as secondary energy carrier is seen as the
key component of a global renewable
world energy supply. |
|
hydrogen
as solar energy carrier
|
solar hydrogen energy economy |
|
hydrogen
energy economy
|
energy
economy where hydrogen
is used as the secondary
energy carrier. |
|
hydrogen
liquefaction
|
liquefaction
of hydrogen,
which is gaseous at room temperature, by cooling
it below -253°C (20 K). |
|
|
combustion
engine which uses hydrogen
as a fuel. |
|
hydrogen
propulsion
|
mobile
propulsion system that uses hydrogen
as fuel. The propulsion energy is produced in
a fuel cell and an
electric motor, in a combustion engine (hydrogen
motor) or a gas turbine. |
|
hydrogen
storage
|
compressed gas storage, cryoadsorption storage, graphite
storage, iron
sponge storage, liquid hydrogen storage, metal hydride storage. |
|
hydrogen jet engine
|
hydrogen fueled jet engine for aviation use |
|
|
iron
sponge can be used as a hydrogen storage material. Hydrogen and rust" (Fe3O4) are converted
into pure iron (iron sponge") which
is transported to the hydrogen consumption site.
In the reverse reaction (oxidation) rust" is produced liberating the hydrogen. The iron
sponge storage can also be filled/ loaded with
synthesis gas (mixture of hydrogen and carbon
monoxide) also liberating pure hydrogen in the
reverse reaction. Iron sponge storage is in
an early stage of development. |
|
LH2
|
liquid hydrogen |
|
LH2
storage
|
liquid hydrogen storage |
|
|
tanks
for the storage of liquids that are gaseous
under normal conditions (room temperature, atmospheric
pressure). The substances are kept in the liquid
phase either by applying a slight over-pressure
(e.g. LPG liquefied petroleum gas; 0.5
- 1.5 MPa) or by storing it at low temperatures
in superinsulated devices (e.g. hydrogen at -253°C). |
|
|
below
-253°C or 20 K hydrogen
is in its liquid phase. |
|
|
liquid gas storage for cryogenic
hydrogen at atmospheric pressure and cryogenic temperatures. |
|
MCFC
|
molten
carbonate fuel cell;
with molten alkaline carbonate electrolyte;
operating temperature 600 to 650°C; fuel: carbon
containing gases (e.g. natural gas, synthesis
gas); state of the art: prototypes are being
manufactured, demonstration planned for the
period 1997 to 2000, first small series production
starting after 2000. |
|
|
device
that can store hydrogen by use of a metal alloy. The hydrogen is soaked
into the alloy like into a sponge and fills
the spaces in the crystal lattice of the alloy.
The storage is filled applying a modest over-pressure
and is usually operated in the temperature range
of 20 - 80°C. |
|
MPa
|
mega
Pascals (SI pressure unit); one MPa corresponds
to a pressure of 10 atmospheres (10 barabs). |
|
PAFC
|
phosphoric
acid fuel cell; with phosphorous electrolyte; operating temperature
160 up to 220°C; fuel: pure hydrogen;
state of the art: 200 kWe systems
commercially available. |
|
partial oxidation
|
conversion
of hydrocarbons (diesel, residual oil etc.)
into a synthesis gas that consists of hydrogen, carbon monoxide (CO) and carbon dioxide (CO2).
The necessary energy is supplied by the combustion
(oxidation") of parts (partial")
of the feedstock in the process itself. Partial
oxidation is a common process for the production
of hydrogen (the synthesis gas is converted
into pure hydrogen by converting the carbon
monoxide and water into carbon dioxide and hydrogen
and by subsequently separating the carbon dioxide). |
|
PEFC
|
PEMFC |
|
|
proton
exchange membrane fuel
cell; with proton conducting membrane as
electrolyte; operating temperature 60 to 80°C;
fuel: pure hydrogen;
state of the art: in 1997 first systems in commercial
operation in the very small power range (>50 W),
larger units in series production for mobile
and stationary applications before the turn
of the century. |
|
photobiological
water splitting
|
there
are different biological processes that liberate
hydrogen or where hydrogen
is produced as an intermediate product. Photobiological
processes as e.g. photosynthesis use the solar
radiation as source of energy, while fermentation
processes that take place in the absence of
light take advantage of the energy stored in
the feedstock (e.g. glucose). There are several
first efforts to use photobiological water splitting
for the technical production of hydrogen. |
|
|
energy carrier to be found in nature (e.g. solar
energy, wood, coal, petroleum, natural gas). |
|
primary
energy carrier
|
primary energy, energy
carrier |
|
|
form
of energy which is never exhausted because it
is renewed by nature (within short time scales;
e.g. wind, solar radiation, hydro power). |
|
renewable
raw material
|
biomass that is only harvested to an extent that allows
a (natural) regeneration. It is used for energetic
or other purposes (e.g. as a construction material). |
|
|
energy carrier which has been produced from primary energy in a conversion process (e.g. electricity,
hydrogen, petrol). |
|
|
secondary energy, energy
carrier |
|
SOFC
|
solid
oxide fuel cell; with oxygen ion conducting ceramic electrolyte;
operating temperature 800 to 1000°C; fuel: pure hydrogen, carbon containing
gases (e.g. natural gas, synthesis gas); state
of the art: first demonstration projects are
presently being carried out, commercialization
planned after 1998. |
|
|
solar
radiation reaching the earth and its use for
the production of electricity and heat. |
|
|
energy
economy where solar
energy is the primary
energy and hydrogen
is used as secondary energy carrier. |
|
SPFC
|
solid
polymer fuel cell = PEMFC |
|
|
device
for steam reforming |
|
|
catalytic
conversion of light hydrocarbons (biomass,
fossil energy carriers e.g. natural gas) producing a synthesis
gas that consists of hydrogen
(H2), carbon monoxide (CO) and methane
(CH4). The process is heat consuming.
Steam reforming of natural gas is a common process
for the production of hydrogen (the synthesis
gas is converted into pure hydrogen by converting
the carbon monoxide and water into carbon dioxide
and hydrogen and by subsequently separating
the carbon dioxide). |